Trichloroisocyanuric acid

製品コードS3632 バッチS363201

化学情報

	Synonyms	N/A	Storage (From the date of receipt)	3 years -20°C powder 1 years -80°C in solvent
	化学式	C₃Cl₃N₃O₃
	分子量	232.41	CAS No.	87-90-1
Solubility (25°C)*	体外	DMSO	46 mg/mL (197.92 mM)
		Water	20 mg/mL (86.05 mM)
		Ethanol	2 mg/mL (8.6 mM)
* <1 mg/ml means slightly soluble or insoluble. * Please note that Selleck tests the solubility of all compounds in-house, and the actual solubility may differ slightly from published values. This is normal and is due to slight batch-to-batch variations.

溶剤液（一定の濃度）を調合する

生物活性

製品説明	Trichloroisocyanuric acid (TCCA) is a safe and efficient reagent, useful for chlorination and oxidation reactions.This product is a hazardous chemical (acute toxicity/flammable/skin corrosive). Please use it while wearing a protective face mask, gloves, and clothing.
in vitro	TCCA has a high solubility in acetone (350 g/L) and ethyl acetate (385 g/L) and a moderate solubility in toluene (70 g/L). TCCA shows in benzylic chlorinations a remarkable selectivity for the monochlorination of different electron-poor heterocycles. The selectivity for the monochlorination of cyclic ethers is also quite good, affording rather good yields of monochlorinated cyclic ethers when used in combination with a catalytic amount of iodine. The R-chlorination of ethers has also been successfully used for the ring-opening of acetals and thioketals. In combination with water, TCCA is a good reagent for hypohalogenation of alkenes. The monochlorination of ketones affords the more substituted R-chloroketone^[1].

製品説明

Trichloroisocyanuric acid (TCCA) is a safe and efficient reagent, useful for chlorination and oxidation reactions.This product is a hazardous chemical (acute toxicity/flammable/skin corrosive). Please use it while wearing a protective face mask, gloves, and clothing.

in vitro

TCCA has a high solubility in acetone (350 g/L) and ethyl acetate (385 g/L) and a moderate solubility in toluene (70 g/L). TCCA shows in benzylic chlorinations a remarkable selectivity for the monochlorination of different electron-poor heterocycles. The selectivity for the monochlorination of cyclic ethers is also quite good, affording rather good yields of monochlorinated cyclic ethers when used in combination with a catalytic amount of iodine. The R-chlorination of ethers has also been successfully used for the ring-opening of acetals and thioketals. In combination with water, TCCA is a good reagent for hypohalogenation of alkenes. The monochlorination of ketones affords the more substituted R-chloroketone^[1].

プロトコル(参考用のみ)

参考

[1] Ulf Tilstam, et al. Org Proc Res Dev, 2002, 6 (4), pp384-393.

長期の保管のために-20°Cの下で製品を保ってください。

人間や獣医の診断であるか治療的な使用のためにでない。

各々の製品のための特定の保管と取扱い情報は、製品データシートの上で示されます。大部分のSelleck製品は、推薦された状況の下で安定です。製品は、推薦された保管温度と異なる温度で、時々出荷されます。長期の保管のために必要とされてそれと異なる温度で、多くの製品は、短期もので安定です。品質を維持するが、夜通しの積荷のために最も経済的な貯蔵状況を用いてあなたの送料を保存する状況の下に、製品が出荷されることを、我々は確実とします。製品の受領と同時に、製品データシートの上で貯蔵推薦に従ってください。